{"id":295085,"date":"2025-05-01T15:24:07","date_gmt":"2025-05-01T15:24:07","guid":{"rendered":"https:\/\/news.talkwithrattan.com\/index.php\/2025\/05\/01\/scientists-home-in-on-alternatives-to-forever-chemicals\/"},"modified":"2025-05-01T15:24:07","modified_gmt":"2025-05-01T15:24:07","slug":"scientists-home-in-on-alternatives-to-forever-chemicals","status":"publish","type":"post","link":"https:\/\/news.talkwithrattan.com\/index.php\/2025\/05\/01\/scientists-home-in-on-alternatives-to-forever-chemicals\/","title":{"rendered":"Scientists home in on alternatives to \u2018forever chemicals\u2019"},"content":{"rendered":"<div style=\"text-align:center\"><\/div> \r\n<br><div data-component=\"video-embed\">\n\t\t\t\t\n\n\n\n\n<p>Harmful and persistent \u201cforever chemicals\u201d build up in the environment and in the bodies of animals \u2014 including humans. But a new review article lays out a blueprint for replacing those chemicals in certain situations.<\/p>\n\n\n\n<p>A research team has compiled more than a decade\u2019s worth of work from multiple labs to detail chemical principles of per- and polyfluoroalkyl substances, otherwise known as PFAS. PFAS show up in products as varied as firefighting foams, nonstick cookware and stain-resistant fabrics. While none of the proposed substitutes outperform existing PFAS yet, the <a href=\"https:\/\/www.sciencedirect.com\/science\/article\/abs\/pii\/S0021979725006010\" target=\"_blank\" rel=\"noreferrer noopener\">best alternatives are approaching the same performance in certain water-repelling applications<\/a>, scientists report in the July 15 <em>Journal of Colloid and Interface Science<\/em>.<\/p>\n\n\n\n<p>PFAS usually contain long chains of carbon atoms. Depending on the chemical, most or all of the carbon atoms have strong bonds to one or more fluorine atoms. Mixed with water, some PFAS act as surfactants, which cause water droplets to spread out rather than beading up, even in the presence of oily chemicals where water normally wouldn\u2019t mix. This behavior relies on properties known as surface energy and surface tension. Molecules in a material with low surface energy or surface tension don\u2019t mind being at the surface of a solid or a droplet of liquid, where come in contact with something dissimilar. PFAS surfactants lower the surface tension of water, so they excel in applications like foams that fight gasoline or grease fires.<\/p>\n\n\n\n<figure class=\"wp-block-image size-full\"><figcaption class=\"wp-element-caption\"><span class=\"caption wp-caption-3154084\">Some fire-fighting foams contain PFAS surfactants, but bulky, tree-branch-like chemicals without fluorine could one day act as surfactants instead.\n<\/span><span class=\"credit wp-credit-3154084\">sunara\/E+\/Getty Images Plus<\/span><\/figcaption><\/figure>\n\n\n\n<p>Alternatively, when used as solid coatings, PFAS force liquids on a surface to bead up into droplets rather than spreading out, which gives PFAS-coated materials like nonstick pans their water- and oil-repelling properties.<\/p>\n\n\n\n<p>But the strong carbon-fluorine bonds in PFAS don\u2019t break down easily, says Julian Eastoe, an interface scientist at the University of Bristol in England. The chemicals steadily accumulate in the environment and <a href=\"https:\/\/www.sciencenews.org\/article\/pfas-forever-chemicals-health-risk-water\">in our bodies<\/a>, a buildup that \u201ccan be considered as one of the great ticking time bombs in our civilization,\u201d Eastoe says. Some researchers are investigating how to <a href=\"https:\/\/www.sciencenews.org\/article\/pfas-forever-chemicals-degrade-lye-chemistry\">break down PFAS<\/a> in the environment, while others \u2014 like Eastoe \u2014 are developing fluorine-free alternatives.<\/p>\n\n\n<aside class=\"sn-conversion rich-text rich-text--with-sidebar\">\n<style><![CDATA[\n.email-conversion {\n  border: 1px solid #ffcccb;\n  color: white;\n  margin-top: 50px;\n  background-image: url(\"\/wp-content\/themes\/sciencenews\/client\/src\/images\/cta-module@2x.jpg\");\n  padding: 20px;\n  clear: both;\n}\n\n]]><\/style>\n\n\n\n<style class=\"is-layout-flow wp-block-group-is-layout-flow\"><![CDATA[#newsletter-helper svg {\n    width: auto;\n    fill: #f1563e;\n}\n\n#newsletter-helper {\n    display: flex;\n    border-top: 1px solid gray;\n    padding-top: 10px;\n    padding-left: 20px;\n    margin-bottom: 10px;\n    max-width: 900px; \n    margin: auto\n}\n\n.zephr-form-container {\n    border-bottom: 1px solid gray;\n    margin: 0px !important;\n}\n]]><\/style><div id=\"newsletter-helper\">\n  <svg xmlns=\"http:\/\/www.w3.org\/2000\/svg\" enable-background=\"new 0 0 122.88 78.607\" height=\"25\" viewbox=\"0 0 122.88 78.607\" width=\"30\"><path clip-rule=\"evenodd\" d=\"m61.058 65.992 24.224-24.221 36.837 36.836h-48.446-25.23-48.443l36.836-36.836zm-59.657-65.992 59.656 59.654 59.657-59.654zm-1.401 69.673 31.625-31.628-31.625-31.625zm122.88 3.025-34.653-34.653 34.653-34.652z\" fill-rule=\"evenodd\"\/><\/svg>\n  <h3 style=\"margin-left: 10px; margin-top:2px; margin-bottom:0px;\">Sign up for our newsletter<\/h3>\n<\/div>\n<p style=\"padding-left: 20px; margin: 0px; max-width: 900px; margin: auto\">We summarize the week&#8217;s scientific breakthroughs every Thursday.<\/p>                        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var(--zephr-input-borderColor);--zf-payment-options-borderRadius:calc(var(--zephr-input-borderRadius) * 1px);--zf-payment-options-highlighted-color:var(--zephr-color-text-main);--zf-payment-options-highlighted-bgColor:var(--zephr-color-accent-main);--zf-payment-summary-fontSize:var(--zf-subtext-fontSize);--zf-payment-summary-color:var(--zephr-color-text-main);--zf-payment-summary-bgColor:var(--zf-input-bgColor);--zf-payment-summary-border:calc(var(--zephr-input-borderWidth) * 1px) solid var(--zephr-input-borderColor);--zf-payment-summary-borderRadius:calc(var(--zephr-input-borderRadius) * 1px);--zf-list-subscriptions-container-maxWidth:630px;--zf-list-subscriptions-container-padding:24px;--zf-list-subscriptions-section-padding:16px 0px;--zf-list-subscriptions-container-border:calc(var(--zephr-input-borderWidth) * 1px) solid var(--zephr-input-borderColor);--zf-list-subscriptions-container-borderRadius:calc(var(--zephr-input-borderRadius) * 1px);--zf-list-subscriptions-info-fontSize:var(--zf-info-fontSize)}.zephr-form.svelte-jjl1p8{color:var(--zf-container-color);margin:var(--zf-container-margin);font-size:var(--zf-root-fontSize);font-family:var(--zf-root-fontFamily)}.zephr-form *{box-sizing:border-box}:where(.zephr-form) button{text-transform:unset;overflow:visible;font-family:var(--zf-root-fontFamily, unset);font-size:var(--zf-root-fontSize, unset);line-height:unset;margin:unset;padding:unset;border:unset;background:unset;&:hover, &:focus-visible {\n            border: unset;\n            background: unset;\n        }}.zephr-form-disabled-div{pointer-events:none;opacity:0.8}.zephr-form-relative-container{position:relative}.zephr-form-flex-container{display:flex}.zephr-form-input-inner-button{cursor:pointer;position:absolute;top:50%;transform:translateY(-50%);right:5px;padding:10px 5px}.zephr-form-input-inner-text{color:var(--zephr-color-text-main);font-size:var(--zf-subtext-fontSize);font-weight:bold;font-family:var(--zf-root-fontFamily)}\n]]><\/style>\n                        \n                        <style><![CDATA[.zephr-form-content {\n    display: flex;\n    flex-wrap: wrap;\n}\n\n.zephr-form-relative-container {\n    flex: 40%\n}\n\n.zephr-form-input {\n    border-radius: 0px !important;\n}\n\n.zephr-form-button {\n    width: 130px !important;\n    margin-top: 0px !important;\n    background-color: #2b3136 !important;\n    text-transform: none !important;\n    font-weight: 900 !important;\n    letter-spacing: 0.075em;\n    font-size: 1.2em !important;\n    border-radius: 0px !important;\n}\n\n.zephr-form-custom-text {\n    width: 100% !important;\n    margin-top: 3px !important;\n}\n\nlabel {\n    display: none !important;\n}\n\n.zephr-form-container {\n    max-height: 130px;\n    max-width: 900px;\n    margin: auto !important;\n    margin-bottom: 20px !important;\n}\n\n.zephr-form {\n    margin: 0px !important;\n    overflow-clip-margin: content-box;\n    --zf-container-bgColor: none;\n    --zf-container-maxWidth: 900px;\n}\n\n.zephr-form h3 {\n    font-size: 1.2rem;\n    font-weight: bold;\n    color: #f1563e;\n    margin-top: 0px;\n}\n\n.zephr-form p {\n    text-align: center;\n    margin: 0px;\n    color: #2b3136;\n    font-size: 1rem;\n}]]><\/style>\n                        \n                        \n<\/aside>\n\n\n<p>To replace PFAS, scientists need to find a way to keep a material\u2019s surface energy low without invoking fluorine. Eastoe and colleagues report that for PFAS acting as surfactants, chains of mostly carbon and silicon atoms with a bulky, tree branch\u2013like structure can take the place of fluorine-rich fragments.<\/p>\n\n\n\n<p>The researchers determined the surface tension of solutions containing water and the fluorine-free surfactants at different concentrations, usually by measuring the force required to pull a metal plate out of each solution. These tests suggest that the surfactants\u2019 \u201cbranches\u201d pack tightly at the surface of a water droplet to reduce the surface tension. Some of the best-performing alternatives reduced the water\u2019s surface tension about as well as PFAS surfactants in use today.<\/p>\n\n\n\n<p>It\u2019s much harder, however, to compete with PFAS in oil-repelling applications. Oils typically spread out easily, so designing a surface coating that rebuffs oils would require a material with a very low surface energy \u2014 a difficult feat without invoking fluorine, says Kevin Golovin, a mechanical engineer at the University of Toronto who was not involved in the work. To effectively repel oils with fluorine-free surfaces, \u201cwe really do need a breakthrough.\u201d<\/p>\n\n\n\n<p>Still, the research could facilitate a transition away from PFAS in certain applications and could help counter perceptions that PFAS cannot be replaced, says Martin Scheringer, a chemist at ETH Zurich who was not involved in the work. \u201cWe need scientists, chemists and materials scientists, who break out of that PFAS track.\u201d<\/p>\n\n\n\n\n\n\n\n\t\t\t<\/div>\r\n<br>\r\n<br><a href=\"https:\/\/www.sciencenews.org\/article\/alternative-forever-chemicals-pfas\">Source link <\/a>","protected":false},"excerpt":{"rendered":"<p>Harmful and persistent \u201cforever chemicals\u201d build up in the environment and in the bodies of animals \u2014 including humans. But a new review article lays out a blueprint for replacing those chemicals in certain situations. A research team has compiled more than a decade\u2019s worth of work from multiple labs to detail chemical principles of [&hellip;]<\/p>\n","protected":false},"author":2,"featured_media":295086,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"tdm_status":"","tdm_grid_status":"","fifu_image_url":"https:\/\/i0.wp.com\/www.sciencenews.org\/wp-content\/uploads\/2025\/04\/042525_sw_PFAS-alternative_inline.jpg?fit=680%2C453&ssl=1","fifu_image_alt":"","footnotes":""},"categories":[606],"tags":[38195,130,148,601],"amp_enabled":true,"_links":{"self":[{"href":"https:\/\/news.talkwithrattan.com\/index.php\/wp-json\/wp\/v2\/posts\/295085"}],"collection":[{"href":"https:\/\/news.talkwithrattan.com\/index.php\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/news.talkwithrattan.com\/index.php\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/news.talkwithrattan.com\/index.php\/wp-json\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"https:\/\/news.talkwithrattan.com\/index.php\/wp-json\/wp\/v2\/comments?post=295085"}],"version-history":[{"count":1,"href":"https:\/\/news.talkwithrattan.com\/index.php\/wp-json\/wp\/v2\/posts\/295085\/revisions"}],"predecessor-version":[{"id":295087,"href":"https:\/\/news.talkwithrattan.com\/index.php\/wp-json\/wp\/v2\/posts\/295085\/revisions\/295087"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/news.talkwithrattan.com\/index.php\/wp-json\/wp\/v2\/media\/295086"}],"wp:attachment":[{"href":"https:\/\/news.talkwithrattan.com\/index.php\/wp-json\/wp\/v2\/media?parent=295085"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/news.talkwithrattan.com\/index.php\/wp-json\/wp\/v2\/categories?post=295085"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/news.talkwithrattan.com\/index.php\/wp-json\/wp\/v2\/tags?post=295085"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}